Beilstein J. Org. Chem.2017,13, 1446–1455, doi:10.3762/bjoc.13.142
facilitates the cleavage of the highly polar Cα–P+ bond.
Keywords: N-(1-arylalkyl)imides; α-imidoalkylating agents; imidoalkylationreactions; 1-imidoalkylphosphonium salts; Tscherniac–Einhorn-type reaction; Introduction
The aminomethylation of C–H acidic compounds by the condensation of non-enolizable
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Graphical Abstract
Scheme 1:
α-Amidoalkylation reactions under basic or acidic conditions.